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Understanding the Hidden Dangers of Combustible Gas and Dust that Causes Explosions in Industrial Settings
Nur Izazi Aliah, January 13, 2025

In recent years, industrial incidents involving combustible gas and dust have captured global attention due to their devastating impact. Fires and explosions from combustible gas and dust have led to significant property damage, injuries, and even fatalities. Understanding the science behind these incidents, the factors contributing to their occurrence, and the measures required to prevent them is critical for ensuring workplace safety.

gas and dust

What is Combustible Gas?

A combustible gas is a gas that can ignite and burn when exposed to an ignition source, such as a spark, flame, or heat. These gases have the potential to form explosive mixtures with air or other oxidizing gases. When the concentration of combustible gas in the air reaches a specific range and is exposed to a heat source, it can lead to a fire or even an explosion.

Combustible gases include a wide array of chemical compounds, each with unique properties and applications. These gases are classified according to the ignitability of the gas/air mixture, as defined in EN/IEC 60079-20-1, which provides guidelines on the explosion hazards of gases. This classification helps industries manage risks and implement appropriate safety measures. Below is a categorized list of common combustible gases and their uses:

Gas GroupsGases are classified according to the ignitability of the gas/air mixture as defined in EN/1EC 60079-20-1
IIIAAcetic, Acid, Acetone, Ammonia, Butane, Cyclohexane, Propane, Gasoline (petrol).
Methane (natural gas, non-mining), Toluene, Xylene.
Methanol (methyl alcohol)
IIIBGroup IIIA gases plus, Di-ethyl ether, Ethylene, Ethanol Methyl ethyk ketone (MEK), Propane-1-ol (n-propyl alcohol)
IIICGroup IIIA and IIIB gases plus, Acetylene, Hydrogen

Hydrocarbon Gases:

  • Methane: Found in natural gas, used in heating and power generation.
  • Propane: A fuel for heating, cooking, and vehicles.
  • Butane: Used in lighters and portable stoves.
  • Cyclohexane: Key in nylon production and other industrial applications.
  • Gasoline Vapors: Emitted from fuels used in transportation.

Oxygenated Compounds:

  • Acetone: A solvent for paints, cleaners, and industrial processes.
  • Methanol: Used in antifreeze, fuel, and chemical synthesis.
  • Methyl Ethyl Ketone (MEK): A solvent in manufacturing and cleaning.

Aromatic Hydrocarbons:

  • Toluene: Common in adhesives, paints, and industrial solvents.
  • Xylene: Used in printing, rubber, and leather industries.

Industrial Gases:

  • Acetylene: A primary gas for welding and cutting operations.
  • Hydrogen: Utilized in refining, fuel cells, and chemical production.
  • Ammonia: Essential for fertilizers, refrigeration, and chemical manufacturing.

Miscellaneous Gases:

  • Acetic Acid: Found in vinegar and used in manufacturing.

Gas Classification per EN/IEC 60079-20-1

This standard categorizes gases into groups and subgroups based on their flammability and explosive potential:

  1. Group I Gases: For underground coal mines where methane (firedamp) is a hazard.
  2. Group II Gases: For surface industries with subdivisions based on minimum ignition energy and maximum experimental safe gaps:
    • IIA: Gases like propane with lower flammability.
    • IIB: Gases such as ethylene with moderate flammability.
    • IIC: Highly explosive gases like hydrogen and acetylene.

This classification allows industries to design explosion-proof systems, choose appropriate equipment, and follow standardized safety protocols.

Area Classification for Gas Zones Based on ATEX/IECEx Markings Explained

There are three area category types, with Category 1 requiring a very high level of protection and defined
as an area having a permanent or prolonged risk of explosions (Zone 0), Category 2 which requires a high
level of protection and has a frequent risk of an explosive mix being present in the air (Zone 1), and
Category 3, specified as requiring a normal level of protection with a small chance of an explosive mix
forming (Zone 2).

Gas ZonesDefinition
Zone 0Explosive atmosphere present continuously or for long periods, frequently
Zone 1Explosive atmosphere is likely to occur under normal conditions, occasionally
Zone 2Explosive atmosphere is unlikely to occur under normal conditions, short periods

What is Combustible Dust?

Combustible dust consists of fine particles of materials that can easily ignite and cause explosions when dispersed in the air and exposed to a heat source or flame. These dust particles are small enough to remain airborne under specific conditions, creating a highly flammable atmosphere. While all types of dust have the potential to be hazardous, combustible dust is hazardous due to its ability to create explosions when ignited.

Dust GroupsDusts are classified by the types of material that make up the dust
IIIACombustible fibres and flyings
IIIBGroup IIIA dusts plus, Non-Conductive Dusts
IIICGroup IIIA and IIIB dusts plus, Conductive Dusts

Group IIIA dust refers to a category of hazardous materials classified under the IECEx or ATEX systems. This classification typically includes non-conductive dusts that are capable of causing a fire or explosion hazard in environments with specific ignition sources. Let's break it down:

1. Group IIIA:-

Combustible Fibres and Flyings

  • Combustible Fibres: These are materials like cotton, wool, hemp, or synthetic fibers that are capable of igniting and burning under certain conditions. While they may not be as finely powdered as dusts, they can still create a significant fire hazard when they accumulate or are suspended in the air.
    • Examples include fibers from textiles, wood, paper, and other natural or synthetic materials.
  • Flyings: These are small particles or fibers that are released into the air during the processing of materials, such as fiberglass or cotton. Flyings can remain suspended in the air for a period of time and may form explosive atmospheres when exposed to an ignition source.

2. Group IIIB:-

Non-Conductive Dusts

  • Non-conductive dusts do not allow electrical current to flow through them, which distinguishes them from conductive dusts like metal or graphite dusts. However, these dusts can still pose significant safety risks if they accumulate in large quantities and become airborne in environments with sources of ignition.
  • Fire and Explosion Hazard: The main concern with non-conductive dust is the possibility of a dust deflagration (rapid combustion). If dust accumulates and is ignited, the combustion can spread rapidly through the suspended dust particles, causing a dangerous explosion.

2. Group IIIC:-

Definition: Group IIIC consists of conductive dusts, such as metal powders (e.g., aluminum or graphite).
This group also includes all dusts classified under IIIA and IIIB.Key Property: Conductive dusts can carry electrical charges, increasing the risk of ignition due to sparks, static discharge, or other electrical phenomena.

Examples: Aluminum dust (conductive), flour dust (from IIIA), and powdered sugar (from IIIB).Hazard: Conductive dusts are highly dangerous in environments with electrical equipment since they can create sparks or short circuits, leading to explosions.

Area Classification for Dust Zones Based on ATEX/IECEx Markings Explained

There are three area category types, with Zone 20 requiring a very high level of protection and defined
as an area having a permanent or prolonged risk of explosions, Zone 21 which requires a high
level of protection and has a frequent risk of an explosive mix being present in the air, and
Zone 22 is specified as requiring a normal level of protection with a small chance of an explosive mix
forming.

Dust ZonesDefinition
Zone 20Explosive atmosphere present continuously or for long periods, frequently
Zone 21Explosive atmosphere is likely to occur under normal conditions, occasionally
Zone 22Explosive atmosphere is unlikely to occur under normal conditions, short periods

The Science Behind Combustible Gas and Dust Explosions

Combustible gas and dust explosions share similar principles, as both occur when a fuel source is mixed with oxygen in the presence of an ignition source and confinement. To understand the process better, we can break it down into the key elements that must align for an explosion to take place. Below is an explanation of each element, specifically for both combustible gas and dust explosions:

1. Fuel: The Combustible Material

Combustible Dust: The fuel in a combustible dust explosion is the dust itself, made up of tiny, fine particles of combustible materials such as wood, sugar, flour, metals (e.g., aluminum), or chemicals. These particles, when suspended in the air, become highly flammable.

Combustible Gas: In the case of combustible gases, the fuel is the gas itself, such as methane, propane, hydrogen, or natural gas. These gases can ignite when mixed with air and exposed to a spark or heat.

2. Oxygen: The Support for Combustion

Combustible Dust: Oxygen from the surrounding air is needed to support the combustion of the dust particles. In a confined or semi-confined space, oxygen concentration can quickly increase, further fueling the explosion.

Combustible Gas: Similarly, oxygen in the air supports the combustion of gases. The right oxygen-to-gas ratio is critical for ignition. Too little oxygen may prevent ignition, while too much can lead to an uncontrollable explosion.

3. Ignition Source: The Trigger for Combustion

Combustible Dust: An ignition source for combustible dust can be sparks, open flames, hot surfaces, or static electricity. In some industrial settings, sparks from machinery or hot exhausts can easily ignite accumulated dust clouds.

Combustible Gas: Combustible gases require a specific ignition source to trigger combustion, such as an electrical spark, open flame, or even a hot surface like an engine exhaust.

4. Confinement: The Presence of a Confined or Semi-Confined Space

Combustible Dust: Combustible dust explosions are more dangerous when they occur in confined or semi-confined spaces, such as silos, hoppers, or even factory buildings. The confined space intensifies the explosion by allowing pressure to build up.

Combustible Gas: Similarly, gas explosions are more dangerous in confined spaces, where gas can accumulate to dangerous levels, creating a potentially explosive environment. Examples include gas leaks in basements, storage tanks, or poorly ventilated rooms.

For both combustible gas and dust explosions to happen, all five elements must align—fuel (gas or dust), oxygen, an ignition source, dispersion (airborne particles or gas), and confinement (a confined or semi-confined space). Understanding each of these factors and how they contribute to explosive incidents is key to preventing such disasters and ensuring workplace safety.

Industries Prone to Combustible Gas and Dust Hazards

Many industries face significant risks from both combustible gases and dust. These hazards can lead to devastating explosions and fires if proper safety measures are not in place. Below is an overview of industries particularly vulnerable to these risks and an explanation of why they are prone to incidents.

1. Agriculture and Food Processing

Sources of Dust: Grain dust, sugar particles, flour, and spices are common examples.
Sources of Gas: Methane from fermentation processes or decomposing organic matter.
Risk Factors: Grain elevators, silos, and processing equipment can confine dust and gas. Ignition sources, like equipment sparks or heat, can easily trigger explosions.

2. Woodworking

Sources of Dust: Sawdust, wood shavings, and fine particles from cutting or sanding operations.
Sources of Gas: Vapors from wood treatments, adhesives, or finishes like varnish and lacquer
Risk Factors: Dust accumulates in confined spaces, while volatile organic compounds (VOCs) from treatments can ignite when exposed to heat or sparks.

3. Chemical Manufacturing

Sources of Dust: Powders, resins, and other fine chemical particulates.
Sources of Gas: Volatile chemicals, flammable vapors, and process byproducts like hydrogen or methane.
Risk Factors: Enclosed spaces, combined with heat, static electricity, or chemical reactions, can create explosive environments.

4. Metals Processing

Sources of Dust: Fine particles from grinding, polishing, or machining metals like aluminum, magnesium, and titanium.
Sources of Gas: Hydrogen gas from metal reactions or industrial processes such as electrolysis.
Risk Factors: Sparks from cutting or welding operations can ignite the flammable gas and dust combination.

5. Oil and Gas Industry

Risk Factors: The presence of volatile gases in confined areas, combined with high-pressure systems and equipment that generate sparks or heat.
Sources of Dust: Fine particles from drilling operations or sand used in hydraulic fracturing.
Sources of Gas: Natural gas, methane, and flammable vapors from crude oil.

6. Textiles

Sources of Dust: Fibers and lint from cotton, wool, or synthetic materials.
Sources of Gas: Vapors from dyeing, bleaching, and other finishing processes.
Risk Factors: Dust accumulation in ventilation systems and volatile gases from treatment processes can ignite with static electricity or overheating.

Industries dealing with both combustible gases and dust face compounded risks that require robust safety measures. Understanding the specific sources of these hazards and implementing targeted strategies, such as effective ventilation, equipment maintenance, and ignition source control, is essential for minimizing the potential for catastrophic incidents.

Root Causes of Combustible Gas and Dust Explosions

1. Poor Housekeeping

The accumulation of combustible dust on surfaces such as machinery, floors, walls, and overhead structures increases the risk of explosions. When disturbed, these layers of dust can become airborne, forming combustible clouds. Similarly, failure to manage leaks of combustible gases can allow them to concentrate to dangerous levels in enclosed areas.

2. Lack of Ventilation

Inadequate air circulation prevents the dispersion of flammable gases and allows dust clouds to form. Poor ventilation can result in the accumulation of hazardous concentrations, making environments highly prone to explosions.

3. Ignition Sources

The presence of ignition sources, such as sparks from electrical equipment, hot surfaces, static electricity, or open flames, significantly contributes to explosion risks. These sources can easily ignite combustible dust clouds or gas mixtures if not adequately controlled.

4. Improper Maintenance

Worn-out or improperly maintained machinery can generate sparks, overheat, or develop leaks, creating ignition points or dispersing combustible materials into the air. Regular equipment checks and preventive measures are essential to avoid these risks.

5. Lack of Awareness

Untrained employees, such as those without IECEx CoPC (Certificate of Personnel Competence) course, can unknowingly create hazards in explosive environments. This globally recognized certification ensures workers are equipped to identify and manage risks effectively, making education essential for preventing accidents and ensuring workplace safety.

By addressing these root causes individually and systematically, industries can significantly reduce the likelihood of combustible gas and dust explosions

The Impact of Combustible Gases and Dust Explosions

Combustible gases and dust explosions leave a trail of destruction that affects lives, property, the environment, and the economy. Here's how:

1. Loss of Life

The intense energy released during an explosion can lead to severe injuries and fatalities, particularly in densely populated work environments. Employees in proximity to the explosion's source are most at risk, making safety protocols critical.

2. Property Damage

Explosions often destroy factories, warehouses, and machinery, leading to expensive repairs or total rebuilds. The damage is not just limited to the affected site; neighboring facilities can also experience significant structural impacts.

3. Environmental Impact

The aftermath of explosions can release harmful chemicals, toxic dust, or flammable gases into the air, water, or soil, contributing to environmental degradation. Cleanup efforts often require significant time and resources.

4. Economic Loss

The financial consequences include production downtime, expensive equipment replacements, and lost revenue. Additionally, businesses face costs related to worker compensation, legal claims, and damage to their reputation.

Understanding the multifaceted impact of such incidents underscores the importance of proactive safety measures and strict adherence to industry standards. Let me know if you'd like this expanded further!

Enhancing Safety Through Explosion-Proof Training

Ultech Engineering is introducing explosion-proof training to East Malaysia in collaboration with Capeserve Energy, a certified trainer for IECEx CoPC (Certificate of Personnel Competence). This partnership aims to provide comprehensive education on managing risks in explosive atmospheres, ensuring personnel are well-equipped to handle hazardous conditions.

The training focuses on international safety standards, hazard identification, and preventive measures, empowering industries to enhance workplace safety and meet compliance requirements. Ultech Engineering and Capeserve Energy are committed to fostering a safer and more competent workforce in East Malaysia through this initiative.

What is IECEx CoPC?

The IECEx Certification of Personnel Competence (CoPC) is a globally recognized certification under the International Electrotechnical Commission (IEC). It is specifically tailored for individuals working in environments with significant risk of fire or explosion. This certification formalizes the individual's possession of the necessary skills, knowledge, and experience to safely perform specific tasks in hazardous environments, thereby reducing the risk of accidents and ensuring compliance with stringent international standards.

IECEx stands for the certification by the International Electrotechnical Commission for Explosive Atmospheres. To be IECEx certified, all products must be monitored by the International Electrotechnical Commission to ensure that they meet the minimum safety requirements. This process will determine whether the products can be used in hazardous or potentially explosive locations.

Being IECEx certified allows the products and equipment to be traded across countries without being re-tested and re-certified for every country. As different countries adhere to different safety standards, products from one country must be re-tested in another country to abide by its guidelines for use in hazardous areas. Therefore, IECEx acts as a common set of safety standards amongst participating countries' certifications, which helps reduce testing and certification costs for manufacturers. Participating countries in the IECEx Scheme include most countries in Europe, Canada, Australia, Russia, China, the United States, and South Africa.

Why is the IECEx CoPC Certification Important?

In industries where explosive atmospheres are a constant threat, personnel competence is not just a regulatory requirement but a vital component of operational safety. The IECEx CoPC certification minimizes risks by ensuring personnel are well-versed in safety protocols and equipped to handle hazardous situations. This certification is vital for oil and gas, petrochemicals, and mining industries, where even a minor oversight can lead to catastrophic consequences.

IECEx CoPC certification example

Strengthening Industrial Safety Through Gas and Dust Hazard Control

Combustible gas and dust explosions are critical industrial hazards that require diligent attention from management, workers, and safety professionals. These incidents can have devastating consequences, including loss of life, property damage, environmental harm, and financial setbacks. Industries can identify vulnerabilities and implement stringent safety measures to mitigate risks by thoroughly understanding the factors contributing to these explosions.

Investing in education and training, such as the IECEx CoPC courses brought to East Malaysia by Ultech Engineering in collaboration with Capeserve Energy, is pivotal in raising awareness and equipping professionals with the skills to manage explosion risks effectively. As industries embrace advanced technology and proactive safety strategies, the vision of eliminating combustible gas and dust incidents moves closer to reality, creating a safer workplace for all.

Contact Ultech Engineering to Improve Safety Against Combustible Dust and Gas Hazards With IECEx CoPC Training and Solutions Today!

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